Selenoxopropadienylidene (CCCSe) as a Bridging Ligand

Bright luminescence in lanthanide coordination polymers with tetrafluoroterephthalate as a bridging ligand.

Ten new coordination polymers of the general compositions ∞²[Ln(III)(tfBDC)(NO3)(DMF)2]·DMF with Ln(III) = Eu(3+) (1), Gd(3+) (2), Tb(3+) (3), Ho(3+) (4), Tm(3+) (5), ∞²[Ln(III)(tfBDC)(CH3COO)(FA)3]·3FA with Ln(III) = Sm(3+) (6), Eu(3+) (7) and ∞²[Ln(III)(tfBDC)(NO3)(DMSO)2] with Ln(III) = Ho(3+) (8), Er(3+) (9) and Tm(3+) (10) were synthesized and structurally characterized by X-ray single cry...

Photoinduced HS state in the first spin-crossover chain containing a cyanocarbanion as bridging ligand.

A new polymeric approach, based on cyanocarbanion ligands, for the design of spin crossover (SCO) compounds led us to the compound [Fe(abpt)(2)(tcpd)] () (tcpd(2-) = (C[C(CN)(2)](3))(2-), abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) which has been characterised as the first SCO molecular chain involving a cyanocarbanion as bridging ligand.

Weblogs as a bridging genre

A neutral Pt3 stack unsupported by any bridging ligand.

Pt···Pt···Pt interactions via their d(8) orbitals, combined with π-π stacking of deprotonated, chelating 2-(3'-pyrazolyl)pyridine (pyzpy) ligands, are responsible for trans-Pt(pyzpy)(2) (2) crystallization in a stack of three molecules unsupported by any bridging ligand.

Synthesis and Magnetism of Copper(II) Binuclear Complexes with Squarate as Bridging Ligand

The study of magnetic exchange interaction propagated by multi-atom bridging is of current interest due to insights into the pathway of electron transfer in biological systems and obtaining some useful information about designing molecule-based magnets [1]. Many papers dealing with squarate as multi-atom bridging ligand have been published [2–14], in which most squarates bridge metal ions in ci...